Booyah! The first Triple Life art post here! So, yes, this is part of my Major Project - I'm working on a visual novel that is also a Sim with a twist. This is a cel sheet full of the lead character's (an Evil Overlord of sorts in real life) myriad expressions.
I'm going to assemble a step-by-step process at some point, but I basically done a rough structural sketch, cleaned it up with a mechanical pencil, and coloured it all in Photoshop. Et voila! Expect more characters soon!
Oh, and the Visual Novel builder I'm using, called Ren'Py can be found here: www.renpy.org